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Asymmetric deprotonation-substitution of n-pop-benzylamines using [rli/(-)-sparteine]. Enantioselective sequential reactions and synthesis of n-heterocycles
dc.contributor.author | Oña Burgos, Pascual | |
dc.contributor.author | Fernández de las Nieves, Ignacio | |
dc.contributor.author | Roces Fernández, Laura | |
dc.contributor.author | García-Granda, Santiago | |
dc.contributor.author | Torre Fernández, Laura | |
dc.contributor.author | López Ortiz, Fernando | |
dc.date.accessioned | 2013-01-30T10:24:44Z | |
dc.date.available | 2013-01-30T10:24:44Z | |
dc.date.issued | 2008 | |
dc.identifier.citation | Organic Letters, 10(15), p. 3195-3198 (2008); doi:10.1021/ol801027p | spa |
dc.identifier.issn | 1523-7060 | |
dc.identifier.uri | http://www.ual.es/~ifernan/pdf/Org_Lett_2008_2.pdf | |
dc.identifier.uri | http://hdl.handle.net/10651/11469 | |
dc.description.abstract | Pop-directed asymmetric deprotonation of benzylic amines using [n-BuLi/(−)-sparteine] provides an efficient method for the synthesis of chiral NCα and NCα,α′ derivatives with total selectivity with respect to competing allylic and ortho lithiation. The method described herein offers a straightforward route of accessing chiral N-Pop-protected nitrogen heterocycles. | spa |
dc.format.extent | p. 3195-3198 | spa |
dc.language.iso | eng | |
dc.relation.ispartof | Organic Letters | spa |
dc.rights | (c) American Chemical Society | |
dc.title | Asymmetric deprotonation-substitution of n-pop-benzylamines using [rli/(-)-sparteine]. Enantioselective sequential reactions and synthesis of n-heterocycles | spa |
dc.type | journal article | |
dc.identifier.local | 20080090 | spa |
dc.identifier.doi | 10.1021/ol801027p | |
dc.relation.publisherversion | http://dx.doi.org/10.1021/ol801027p | spa |
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