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Asymmetric deprotonation-substitution of n-pop-benzylamines using [rli/(-)-sparteine]. Enantioselective sequential reactions and synthesis of n-heterocycles

dc.contributor.authorOña Burgos, Pascual
dc.contributor.authorFernández de las Nieves, Ignacio
dc.contributor.authorRoces Fernández, Laura 
dc.contributor.authorGarcía-Granda, Santiago 
dc.contributor.authorTorre Fernández, Laura 
dc.contributor.authorLópez Ortiz, Fernando
dc.date.accessioned2013-01-30T10:24:44Z
dc.date.available2013-01-30T10:24:44Z
dc.date.issued2008
dc.identifier.citationOrganic Letters, 10(15), p. 3195-3198 (2008); doi:10.1021/ol801027pspa
dc.identifier.issn1523-7060
dc.identifier.urihttp://www.ual.es/~ifernan/pdf/Org_Lett_2008_2.pdf
dc.identifier.urihttp://hdl.handle.net/10651/11469
dc.description.abstractPop-directed asymmetric deprotonation of benzylic amines using [n-BuLi/(−)-sparteine] provides an efficient method for the synthesis of chiral NCα and NCα,α′ derivatives with total selectivity with respect to competing allylic and ortho lithiation. The method described herein offers a straightforward route of accessing chiral N-Pop-protected nitrogen heterocycles.spa
dc.format.extentp. 3195-3198spa
dc.language.isoeng
dc.relation.ispartofOrganic Lettersspa
dc.rights(c) American Chemical Society
dc.titleAsymmetric deprotonation-substitution of n-pop-benzylamines using [rli/(-)-sparteine]. Enantioselective sequential reactions and synthesis of n-heterocyclesspa
dc.typeinfo:eu-repo/semantics/article
dc.identifier.local20080090spa
dc.identifier.doi10.1021/ol801027p
dc.type.dcmitextspa
dc.relation.publisherversionhttp://dx.doi.org/10.1021/ol801027pspa


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