dc.contributor.author | Popovici, Cristinel | |
dc.contributor.author | Oña Burgos, Pascual | |
dc.contributor.author | Fernández de las Nieves, Ignacio | |
dc.contributor.author | Roces Fernández, Laura | |
dc.contributor.author | García-Granda, Santiago | |
dc.contributor.author | Iglesias Valdés-Solís, María José | |
dc.contributor.author | López Ortiz, Fernando | |
dc.date.accessioned | 2013-01-30T10:06:11Z | |
dc.date.available | 2013-01-30T10:06:11Z | |
dc.date.issued | 2010 | |
dc.identifier.citation | Organic Letters, 12(3), p. 428-431 (2010); doi:10.1021/ol902545q | spa |
dc.identifier.issn | 1523-7060 | |
dc.identifier.uri | http://hdl.handle.net/10651/8081 | |
dc.description.abstract | Asymmetric ortho-lithiation of N-dialkyl-P,P-diphenylphosphinamides using [n-BuLi·(−)-sparteine] is described as an efficient method for the synthesis of P-chiral ortho-functionalized derivatives in high yields and ee’s from 45 to >99%. The method allows access to new enantiomerically pure P-chiral phosphine and diimine ligands. | spa |
dc.format.extent | p. 428-431 | spa |
dc.language.iso | eng | |
dc.relation.ispartof | Organic Letters | spa |
dc.rights | (c)American Chemical Society | |
dc.source | Scopus | spa |
dc.source.uri | http://www.scopus.com/inward/record.url?eid=2-s2.0-75749117843&partnerID=40&md5=75a7e78d1297e6eb832e61ee3be9af34 | |
dc.title | Enantioselective desymmetrization of diphenylphosphinamides via (-)-sparteine-mediated ortho-lithiation. synthesis of P-chiral ligands | spa |
dc.type | journal article | |
dc.identifier.local | 20100382 | spa |
dc.identifier.doi | 10.1021/ol902545q | |
dc.relation.publisherversion | http://dx.doi.org/10.1021/ol902545q | spa |