Expanding the regioselective enzymatic repertoire: oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta
Publication date:
2012
Editorial:
Royal Society of Chemistry
Publisher version:
Citación:
Chemical Communications, 48, p. 3303–3305 (2012); doi:10.1039/c2cc17572j
Descripción física:
p. 3303-3305
Abstract:
The first report of a biocatalytic regioselective oxidative monocleavage of dialkenes was successfully achieved employing a cellfree enzyme preparation from Trametes hirsuta at the expense of molecular oxygen. Selected reactions were performed on a preparative scale affording high to excellent conversions and chemoselectivities
DOI:
Patrocinado por:
This project is supported by the BIOTRAINS Marie Curie Initial Training Network, financed by the European Union through the 7th Framework People Programme (grant agreement number 238531). Financial support from the Spanish MICINN (Project CTQ-2007-61126) is also gratefully acknowledged. I.L. and V.G.-F. acknowledge MICINN for their research contracts under the Ramo´ n y Cajal Program
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