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Synthesis and Characterization of a Coupled Binuclear Cu-I/Cu-III Complex

Author:
García López, Jesús; Yañez Rodríguez, Víctor; Roces Fernández, LauraUniovi authority; García-Granda, SantiagoUniovi authority; Martínez Vázquez, Ana; Guevara García, Alfredo; Castro Castro, Germán Rafael
Publication date:
2010
Publisher version:
http://dx.doi.org/10.1021/ja1034667
Citación:
Journal of the American Chemical Society, 132(31), p. 10665-10667 (2010); doi:10.1021/ja1034667
Descripción física:
p. 10665-10667
Abstract:

The synthesis through reaction of a Cα,Cortho dilithiated phosphazene with CuBr and structural characterization of the first example of a binuclear mixed valence [CuI(N2)/CuIII(C4)] complex showing a metal−metal bond, as well as its applications in cyclopropanation and oxidation reactions, are described.

The synthesis through reaction of a Cα,Cortho dilithiated phosphazene with CuBr and structural characterization of the first example of a binuclear mixed valence [CuI(N2)/CuIII(C4)] complex showing a metal−metal bond, as well as its applications in cyclopropanation and oxidation reactions, are described.

URI:
http://hdl.handle.net/10651/10034
ISSN:
0002-7863
Identificador local:

20100318

DOI:
10.1021/ja1034667
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