Synthesis and Characterization of a Coupled Binuclear Cu-I/Cu-III Complex
Publication date:
2010Publisher version:
http://dx.doi.org/10.1021/ja1034667Citación:
Journal of the American Chemical Society, 132(31), p. 10665-10667 (2010); doi:10.1021/ja1034667Descripción física:
p. 10665-10667Abstract:
The synthesis through reaction of a Cα,Cortho dilithiated phosphazene with CuBr and structural characterization of the first example of a binuclear mixed valence [CuI(N2)/CuIII(C4)] complex showing a metal−metal bond, as well as its applications in cyclopropanation and oxidation reactions, are described.
ISSN:
0002-7863Identificador local:
20100318
DOI:
10.1021/ja1034667Collections
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