Repositorio Institucional de la Universidad de Oviedo

Synthesis and Characterization of a Coupled Binuclear Cu-I/Cu-III Complex

Autor(es) y otros:

García López, Jesús; Yañez Rodríguez, Víctor; Roces Fernández, Laura

; García-Granda, Santiago

; Martínez Vázquez, Ana; Guevara García, Alfredo; Castro Castro, Germán Rafael

Fecha de publicación:

2010

Versión del editor:

http://dx.doi.org/10.1021/ja1034667

Citación:

Journal of the American Chemical Society, 132(31), p. 10665-10667 (2010); doi:10.1021/ja1034667

Descripción física:

p. 10665-10667

Resumen:

The synthesis through reaction of a Cα,Cortho dilithiated phosphazene with CuBr and structural characterization of the first example of a binuclear mixed valence [CuI(N2)/CuIII(C4)] complex showing a metal−metal bond, as well as its applications in cyclopropanation and oxidation reactions, are described.

The synthesis through reaction of a Cα,Cortho dilithiated phosphazene with CuBr and structural characterization of the first example of a binuclear mixed valence [CuI(N2)/CuIII(C4)] complex showing a metal−metal bond, as well as its applications in cyclopropanation and oxidation reactions, are described.

URI:

http://hdl.handle.net/10651/10034

ISSN:

Identificador local:

20100318

DOI:

10.1021/ja1034667

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