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Fluorescent conjugated polymers for chemical and biochemical sensing

Autor(es) y otros:
Álvarez Díaz, AdriánAutoridad Uniovi; Salinas Castillo, Alfonso; Costa Fernández, José ManuelAutoridad Uniovi; Pereiro García, María RosarioAutoridad Uniovi; Sanz Medel, AlfredoAutoridad Uniovi
Palabra(s) clave:

Biochemical Sensing; Chemical Sensing; Conjugated Polymer; Conjugated Polyelectrolyte; Dna Sensing; Explosives Sensing; Fluorescence; Fluorescence Resonance Energy Transfer (Fret); Metal-Ion Sensing; Molecular Wire Effect

Fecha de publicación:
2011
Versión del editor:
http://dx.doi.org/10.1016/j.trac.2011.04.017
Citación:
Trac-Trends in Analytical Chemistry, 30(9), p. 1513-1525 (2011); doi:10.1016/j.trac.2011.04.017
Descripción física:
p. 1513-1525
Resumen:

This review deals with the emerging field of fluorescent conjugated polymers for the development of chemical and/or biochemical sensors. As a result of their amplified physical properties due to a “molecular wire effect”, these materials offer excellent characteristics to develop different sensing schemes (e.g., employing direct superquenching or relying on development of fluorescence-resonance-energy-transfer formats). The versatility of their synthesis procedures allows us to introduce the desired functional groups to achieve analytically useful interactions with analytes [e.g., from transition-metal ions to explosives, or even, in recent years, relevant biomolecules (e.g., proteins or DNA, where conformational changes play a decisive role in detection)].

This review deals with the emerging field of fluorescent conjugated polymers for the development of chemical and/or biochemical sensors. As a result of their amplified physical properties due to a “molecular wire effect”, these materials offer excellent characteristics to develop different sensing schemes (e.g., employing direct superquenching or relying on development of fluorescence-resonance-energy-transfer formats). The versatility of their synthesis procedures allows us to introduce the desired functional groups to achieve analytically useful interactions with analytes [e.g., from transition-metal ions to explosives, or even, in recent years, relevant biomolecules (e.g., proteins or DNA, where conformational changes play a decisive role in detection)].

URI:
http://hdl.handle.net/10651/7889
ISSN:
0165-9936
Identificador local:

20110977

DOI:
10.1016/j.trac.2011.04.017
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