Addition of allyl grignard to nitriles in air and at room temperature: experimental and computational mechanistic insights in ph-switchable synthesis

J. G. A. thanks MCIN/AEI/10.13039/501100011033 (project numbers CTQ2016-75986-P, RED2018-102387-T and PID2020113473GB-I00) for financial support. D. E., F. C.-H., and B. PC. acknowledge financial support from MCIN/AEI/10.13039/ 501100011033 (project numbers PID2020-117353GB-I00 and RED2018-102387-T) and the Universidad de Castilla-La Mancha (project number 2022-GRIN-34031). D. E. thanks the Junta de Comunidades de Castilla-La Mancha and EU for financial support through the European Regional Development Fund (ERDF; project SBPLY/19/180501/000137). I. F. thanks the Spanish MCIN/AEI/10.13039/501100011033 (grants PID2019106184GB-I00 and PID2022-139318NB-I00).