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Synthesis and Se-Se Bond Breaking of Polyselenides Containing Pendant Diphosphine Complexes of Manganese(I)(+)
dc.contributor.author | Ruiz Cabezas, Javier | |
dc.contributor.author | Araúz Montenegro, René | |
dc.contributor.author | Ceroni Galloso, Mario | |
dc.contributor.author | Vivanco Fernández, Marilín | |
dc.contributor.author | Van der Maelen Uría, Juan Francisco | |
dc.contributor.author | García-Granda, Santiago | |
dc.date.accessioned | 2013-01-30T10:00:55Z | |
dc.date.available | 2013-01-30T10:00:55Z | |
dc.date.issued | 2010 | |
dc.identifier.citation | Organometallics, 29(13), p. 3058-3061 (2010); doi:10.1021/om100229q | spa |
dc.identifier.issn | 0276-7333 | |
dc.identifier.uri | http://hdl.handle.net/10651/6999 | |
dc.description.abstract | Reaction of [Mn(CO)4{(PPh2)2CH}] (1) with half an equivalent of dipiperidinotetraselane affords the tetraselenide compound [(CO)4Mn{(PPh2)2C-Se4-C(PPh2)2}Mn(CO)4] (2-Se4), which, upon treatment with KOH, is transformed into the corresponding triselenide and diselenide derivatives 2-Se3 and 2-Se2. Full or partial protonation of the methanide carbon atoms can be accomplished by reaction of the above compounds with HBF4, whereas treatment of 2-Se2 with I2 gives rise to the formation of the selenelyl iodide derivative [Mn(CO)4{(PPh2)2C-Se-I}] (5). | spa |
dc.format.extent | p. 3058-3061 | spa |
dc.language.iso | eng | |
dc.relation.ispartof | Organometallics | spa |
dc.rights | (c) American Chemical Society | |
dc.source | WOK | spa |
dc.title | Synthesis and Se-Se Bond Breaking of Polyselenides Containing Pendant Diphosphine Complexes of Manganese(I)(+) | spa |
dc.type | journal article | |
dc.identifier.local | 20100248 | spa |
dc.identifier.doi | 10.1021/om100229q | |
dc.relation.publisherversion | http://dx.doi.org/10.1021/om100229q | spa |
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