Merging gold catalysis and haloethynyl frames: emphasis on halide-shift processes
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Haloalkynes can enter a wide variety of metal-catalyzed transformation giving rise to the formation of products with or without showing halide-shift. This article offers an overall view of the reactivity of these substrates under gold catalysis. Particular attention is devoted to intramolecular reactions that involve a concomitant halide-shift process for the case of alkynyl iodides as starting materials.
Haloalkynes can enter a wide variety of metal-catalyzed transformation giving rise to the formation of products with or without showing halide-shift. This article offers an overall view of the reactivity of these substrates under gold catalysis. Particular attention is devoted to intramolecular reactions that involve a concomitant halide-shift process for the case of alkynyl iodides as starting materials.
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OA ATUO22
Patrocinado por:
Agencia Estatal de Investigacion (AEI) , Fondo Europeo de Desarrollo Regional (FEDER) [CTQ2016-76840-R]; AEI [PID2019-107469RB-I00/AEI/10.13039/501100011033]; Spanish Ministerio de Economia Industria y Competitividad; Spanish MINECO [RyC-2016-20951]
Id. Proyecto:
AEI/FEDER/UE/ CTQ2016-76840-R
AEI/PID2019-107469RB-I00
MINECO/RyC-2016-20951
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