1,2-Diphenyl-2-(m-tolylamino)ethanone

The title compound, C21H19NO, belongs to the family of -amino-ketones. The structure contains three benzene rings, two of which [the phenyl ring in the 1-position (B) and the methylaniline ring (A)] are nearly coplanar [dihedral angle = 5.4 (1)°], whereas the phenyl ring in the 2-position (C) is nearly normal to them [dihedral angles = 81.8 (1) and 87.0 (1)° for A/C and B/C, respectively]. The conformation of the N - H bond is syn to the C=O bond, favouring the formation of a centrosymmetric dimer of molecules in the crystal structure. The molecular packing is consolidated by this N - H⋯O hydrogen-bonding network.

URI:

http://hdl.handle.net/10651/6534

ISSN:

1600-5368

Identificador local:

20100083

DOI:

10.1107/S1600536810013371

Patrocinado por:

Financial support by the Agencia Española de Cooperación Internacional y Desarrollo (AECID), FEDER funding, the Spanish MICINN (MAT2006–01997 and Factoría de Cristalización Consolider Ingenio 2010) and the Gobierno del Principado de Asturias (PCTI) is acknowledged.