Fast and Chemoselective Addition of Highly Polarized Lithium Phosphides Generated in Deep Eutectic Solvents to Aldehydes and Epoxides

L.C. and J.G.A thank the Spanish MINECO (Project CTQ2016-75986-P and CTQ2016-81797-REDC). A.F. A.S.-C., G.A.C and A.P.Sare indebted to Spanish MINECO (Project CTQ2014-56345-P,CTQ2017-88357-P, and RYC-2012-09800), and Gobierno delPrincipado de Asturias (FICYT, Project FC-15-GRUPIN14-106) forfinancial support. A.P.S. is also grateful to the COST action SmartInorganic Polymers (SIPs-CM1302 – http://www.sips-cost.org/home/index.html), and Spanish MEC for the Juan de la Cierva and Ramón y Cajal programs. J. G.-A. thanks: i) the Fundación BBVAfor the award of a “Beca Leonardo a Investigadores y Creadores Culturales 2017”;[33]and ii) PhosAgro/UNESCO/IUPAC for the awardof a “Green Chemistry for Life Grant”. This work was carried out under the framework of the project “Development of Sustainable Synthetic Processes in Unconventional Solvents for the Preparationof Molecules of Pharmaceutical Interest” realized with the contribution of Fondazione Puglia, which is gratefully acknowledged by L.C. and V.C.