Mixed-valence μ3-oxo-centered triruthenium cluster [Ru3 (II,III,III)(μ3-O)(μ-CH3CO2)6(H2O)3]·2H2O: Synthesis, structural characterization, valence-state delocalization and catalytic behavior
Publication date:
2016
Publisher version:
Citación:
Inorganica Chimica Acta, 454, p. 107-116 (2016); doi:10.1016/j.ica.2016.05.046
Descripción física:
p. 107-116
ISSN:
Patrocinado por:
The authors thank FEDER and Spanish MINECO for financial support under projects MAT2013-40950-R, Consolider ORFEO. A.D. also thanks to Spanish Ministerio de Educación, Cultura y Deporte by their pre-doctoral FPU grant (AP2008-03942). The synchrotron measurement time was provided by ESRF (Grenoble, France) within the research project No. CH-3428. The authors thank staff members of BM25 (SpLine): Dr. Germán R. Castro, Dr. Iván Da Silva González and Dr. Pilar Ferrer Escorihuela for the technical support, guidance and useful suggestions on XANES data collection at the synchrotron facility.
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