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Mononuclear biscarbene complexes by direct nucleophile addition to a CO ligand of Fischer arylcarbene complexes

Autor(es) y otros:
Barluenga Mur, JoséAutoridad Uniovi; Trabanbco Suárez, Andrés Avelino; Pérez Sánchez, IvánAutoridad Uniovi; Campa Fernández, Raquel de laAutoridad Uniovi; Flórez González, JosefaAutoridad Uniovi; García-Granda, SantiagoAutoridad Uniovi; Aguirre Pérez, ÁngelAutoridad Uniovi
Palabra(s) clave:

Diene Ligands; Alkenyllithiums; Carbene–Carbene Coupling; Carbenes; Nucleophilic Addition

Fecha de publicación:
2008
Versión del editor:
http://dx.doi.org/10.1002/chem.200800452
Citación:
Chemistry - A European Journal, 14(18), p. 5401–5404 (2008); doi:10.1002/chem.200800452
Descripción física:
p. 5401-5404
Resumen:

The unusual addition of some nucleophiles to a CO ligand of Fischer aryl carbene complexes has been developed and represents a novel and efficient approach to achieve once again the CO ligand → carbene ligand conversion. The potential of this methodology for the stereoselective synthesis of electron-rich 1,3-dienes is presented

The unusual addition of some nucleophiles to a CO ligand of Fischer aryl carbene complexes has been developed and represents a novel and efficient approach to achieve once again the CO ligand → carbene ligand conversion. The potential of this methodology for the stereoselective synthesis of electron-rich 1,3-dienes is presented

URI:
http://hdl.handle.net/10651/11134
ISSN:
0947-6539
Identificador local:

28

DOI:
10.1002/chem.200800452
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