Data Documentation for the supplemetary material of the article "Visible-light-driven synthesis of alkenyl thiocyanates: novel building blocks for assembly of diverse sulfur-containing molecules". Chemical Science, doi: 10.1039/D4SC06550F General Information Supplementary information for the article "Visible-light-driven synthesis of alkenyl thiocyanates: novel building blocks for assembly of diverse sulfur-containing molecules". Chemical Science, doi: 10.1039/D4SC06550F. The data are contained in a word .docx file with the chemdraw and NMR data embebed. NMR data in mestrenova format can be retrieved from the file. Name of dataset: Supplementary Information revised Name of data files in data set: Supplementary Information revised.doc Dataset language: English Date the data set was last modified: 21-10-2024 Funder: A “Severo Ochoa” predoctoral fellowship (BP21/050) to H. F. P. by FICYT (Principality of Asturias) and a “Ram´ on y Cajal” postdoctoral grant to M. P. (MCINN-24-RYC2022-035485-I) by Ministerio de Ciencia e Innovaci´ on of Spain (Agencia Estatal de Investigaci´ on) are gratefully acknowledged. Financial support of this work by Ministerio de Ciencia e Innovaci´ on of Spain (Agencia Estatal de Investigaci´ on: MCINN-23-PID2022140635NB-I00/MCIN/AEI/10.13039/501100011033/FEDER, UE) and the University of Oviedo (PAPI-23-GR-COM-04) is also acknowledged. How to cite data: Fernández Piedra, H.; Plaza, M. Visible-light-driven synthesis of alkenyl thiocyanates: novel building blocks for assembly of diverse sulfur-containing molecules. Chem. Sci., 2024,15, 19077-19083. https://doi.org/10.1039/D4SC06550F Methodology for data collection: Data collector(s): Helena Fernández Piedra Date of data collection: 2024 Person to contact with questions: Manuel Plaza Data entry: 13-05-2025 Software (including version #) used to prepare data set: MSword, Chemdraw22.2, MestreNova 14 Data processing that was performed: NMR FIDs were processed with MestreNova, copied and pasted in the Word document Variables File Overview Supplementary Information revised: a .docx file containing all the experimental and NMR data,: NMR mestrenova files can be retrieved oorm the document.