Data Documentation for the supplemetary material of the article "A Continuous-Flow Protocol for the Synthesis of Alkenyl Thioethers Based on the Photochemical Activation of Halogen-Bonding Complexes". Synlett, doi: 10.1055/a-2346-1091. General Information Supplementary information for the article "A Continuous-Flow Protocol for the Synthesis of Alkenyl Thioethers Based on the Photochemical Activation of Halogen-Bonding Complexes". Synlett, doi: 10.1055/a-2346-1091. The data are contained in a word .docx file with the chemdraw and NMR data embebed. NMR data in mestrenova format can be retrieved from the file. Name of dataset: Supplementary Information revised Name of data files in data set: Supplementary Information revised.doc Dataset language: English Date the data set was last modified: 13-06-2024 Funder: “Severo Ochoa” predoctoral fellowship to H. F. P. (BP21/050) by FICYT (Principality of Asturias). “Ramón y Cajal” postdoctoral grant to M. P. (MCINN-24-RYC2022- 035485-I) by Ministerio de Ciencia e Innovación of Spain (Agencia Estatal de Investigación). This work is funded by the University of Oviedo (PAPI-23-GR-COM-04) and Ministerio de Ciencia e Innovación of Spain (MCINN-23-PID2022- 140635NB-I00 / MCIN / AEI / 10.13039/501100011033/FEDER, UE). How to cite data: Fernández Piedra, H.; Valdés, C.; Plaza, M. A Continuous-Flow Protocol for the Synthesis of Alkenyl Thioethers Based on the Photochemical Activation of Halogen-Bonding Complexes". Synlett, 2024, a-2346-1091. DOI: 10.1055/a-2346-1091 Methodology for data collection: Data collector(s): Helena Fernández Piedra Date of data collection: 2024 Person to contact with questions: Manuel Plaza Data entry: 13-05-2025 Software (including version #) used to prepare data set: MSword, Chemdraw22.2, MestreNova 14 Data processing that was performed: NMR FIDs were processed with MestreNova, copied and pasted in the Word document Variables File Overview Supplementary Information revised: a .docx file containing all the experimental and NMR data,: NMR mestrenova files can be retrieved oorm the document.