Data Documentation for the supplemetary material of the article "Synthesis of Vinyl and 1,3-Dienyl Sulfones Enabled by Photochemical Excitation of Halogen-Bonding Complexes". Advanced Synthesis & Catalysis, doi: 10.1002/adsc.202301381 General Information Supplementary information for the article "Synthesis of Vinyl and 1,3-Dienyl Sulfones Enabled by Photochemical Excitation of Halogen-Bonding Complexes". Advanced Synthesis & Catalysis, doi: 10.1002/adsc.202301381 The data are contained in a word .docx file with the chemdraw and NMR data embebed. NMR data in mestrenova format can be retrieved from the file. Name of dataset: Supplementary Information revised Name of data files in data set: Supplementary Information revised.doc Dataset language: English Date the data set was last modified: 26-12-2023 Funder: We are thankful for the financial support of this work by a FICYT (Principality of Asturias) “Margarita Salas Joven” postdoctoral grant to M. P. (AYUD/2021/58397), Universidad de Oviedo (PAPI-23-GR-COM-04) and Ministerio de Ciencia e Innovación of Spain (Agencia Estatal de Investigación: PID2019-107580GB-I00/AEI/10.13039/501100011033 and MCINN-23-PID2022-140635NB-I00/MCIN/AEI/10.13039/501100011033/FEDER, UE). A “Severo Ochoa” predoctoral fellowship to H. F. P. (BP21/050) by FICYT (Principality of Asturias) is also gratefully acknowledged. How to cite data: Fernández Piedra, H.; Valdés, C.; Plaza, M. Synthesis of Vinyl and 1,3-Dienyl Sulfones Enabled by Photochemical Excitation of Halogen-Bonding Complexes. Adv. Synth. Catal. 2024, 366, 1422-1429. https://doi.org/10.1002/adsc.202301381 Methodology for data collection: Data collector(s): Helena Fernández Piedra Date of data collection: 2023 Person to contact with questions: Manuel Plaza Data entry: 13-05-2025 Software (including version #) used to prepare data set: MSword, Chemdraw22.2, MestreNova 14 Data processing that was performed: NMR FIDs were processed with MestreNova, copied and pasted in the Word document Variables File Overview Supplementary Information revised: a .docx file containing all the experimental and NMR data,: NMR mestrenova files can be retrieved oorm the document.