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Please use this identifier to cite or link to this item: http://hdl.handle.net/10651/7292

Title: Organic-inorganic hybrids assembled from lanthanide and 1,4-phenylenebis(phosphonate)
Author(s): Amghouz, Zakariae
García-Granda, Santiago
García Menéndez, José Rubén
Clearfield, Abraham
Valiente, Rafael
Issue date: 2011
Publisher version: http://dx.doi.org/10.1021/cg2008254
Citation: Crystal Growth and Design, 11(12), p. 5289-5297 (2011); doi:10.1021/cg2008254
Format extent: p. 5289-5297
Abstract: A series of novel organic–inorganic hybrids based on trivalent lanthanide (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho) and 1,4-phenylbis(phosphonate) formulated as Ln[O3P(C6H4)PO3H] has been obtained as single phases under hydrothermal conditions. In the praseodymium compound (Za1), single crystals have been obtained and the crystal structure has been determined. Za1 crystallizes in the monoclinic space group, C2/c, with a = 5.6060(4) Å, b = 20.251(7) Å, c = 8.2740(6) Å, β = 108.52(1)°. All other compounds are isostructural to Za1 as confirmed by Rietveld refinement using X-ray powder diffraction data. Compounds are characterized by thermal analyses (TG-MS and SDTA), elemental analysis, IR spectra, and X-ray thermodiffraction analysis. Their visible photoluminescence properties are also discussed.
URI: http://hdl.handle.net/10651/7292
ISSN: 1528-7483
Local identifier: 20111889
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