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Please use this identifier to cite or link to this item: http://hdl.handle.net/10651/54887

Title: First Desymmetrization of 1,3-Propanediamine Derivatives in Organic Solvent. Development of a New Route for the Preparation of Optically Active Amines§
Author(s): Busto García, Benjamín Eduardo
Gotor Fernández, Vicente
García-Granda, Santiago
Gotor Santamaría, Vicente Miguel
Issue date: 2007
Publisher version: https://doi.org/10.1021/ol701720m
Citation: Organic Letters, 9(21), p. 4203–4206 (2007); doi:10.1021/ol701720m
Format extent: p. 4203–4206
Abstract: The chemical synthesis and enzymatic desymmetrization of a panel of prochiral diamines have been successfully described for the first time using lipases in organic solvents. A family of 2-aryl-1,3-propanediamines has been obtained with high enantiopurity and good yields in the PSL-catalyzed reaction using diallyl carbonate in 1,4-dioxane.
URI: http://hdl.handle.net/10651/54887
ISSN: 1523-7060
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