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Structure, Bonding, and Reactivity of Binuclear Complexes Having Asymmetric Trigonal Phosphinidene Bridges:Addition of 16-Electron Metal Carbonyl Fragments to the Dimolybdenum Compounds [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2L]and [Mo2Cp2(μ-PH)(CO)2L] (L = η6-1,3,5-C6H3tBu3)
We thank the DGI of Spain (Projects CTQ2006-01207 and CTQ2009-09444) and the COST Action CM0802 ‘‘PhoSciNet’’ for supporting this work, and the Universidad de Oviedo and the Consejería de Educación of Asturias for grants (to I.A. and J.S.). We also thank the Universidad de Santiago de Compostela(Spain) for the acquisition of the X-ray diffraction data.